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uE4006 Nanotechnology

Module Objective: To describe the principles and fundamental building blocks of key nanoscale devices and technologies.

Module Content: Nanoelectronics: Introduction to low dimensional physics; transport in low dimensional systems; heterostructure devices; quantum device operation. Nanophotonics: Band structure engineering for photonic devices; photonic device fabrication technologies; survey of key devices: LEDs, RCLEDs, VCSELs, microdisks, quantum dot devices, single photon devices. Emerging technologies: Mesoscopic physics: wave function coherence, tunnelling; devices based on ballistic transport, single charge tunnelling, resonant tunnelling; fabrication and assembly at the nanoscale; nanoscale visualisation and characterisation; molecular scale electronic devices.

"Nanoelectronics" (16 lectures - Aidan Quinn)

Introduction

  • Nanotechnology’s potential
  • International Technology Roadmap for Semiconductors
  • Top-down vs Bottom-up
  • Quantum Mechanics Overview
  • Electron Tunneling

Nanoscale visualisation

  • Electron microscopy: SEM, TEM  
  • Scanning probe microsopy and spectroscopy: STM, AFM, NSOM

CMOS scaling

  • Lithography  
  • Materials
  • Interconnects
  • MOSFET device scaling

Low dimensional physics

  • 2D, 1D, 0D electron gases
  • Electron transport in low dimensional systems
  • Ballistic transport, scattering and mobility
  • Conductance quantisation

Quantum devices

  • Tunneling: single barrier, double barrier

  • Resonant tunneling devices
  • Single electron tunneling
  • Single electron devices

Bottom-up fabrication: Nanocrystals  

  • Synthesis
  • Optical and electrical properties
  • Non-classical CMOS nanocrystal devices

C60 and carbon nanotubes

  • Synthesis of C60 and nanotubes
  • Nanotubes as interconnects
  • Nanotubes as transistors/logic devices

Semiconductor nanowires

  • Synthesis
  • Nanowire devices
  • Nanowire circuits

Molecular electronics

Bottom-up assembly

Review & outlook  


CM3103 Environmental Science & Technology

Module Objective: To describe how physical chemistry is the key to the development of new technology relevant to the environment.

Module Content: The development and use of: (i) clean solvents such as supercritical CO2; (ii) heterogeneous catalysts, for example in automotive exhausts; (iii) electrochemical methods in energy conversion and fuel cells.

"Impact of Nanotecnnology and Materials" (10 lectures - Alan O'Riordan)

Introduction

  • Nanotechnology’s potential
  • Length scales
  • Materials: Semiconductor nanocrystals, conjugated polymers
  • Application areas

Structure and Bonding 

  • Atomic orbitals
  • Energy levels
  • Bond formation – s and p bonds
  • Molecular orbitals
  • Delocalisation

The Solid State

  • Structure: Unit cells, Bravais lattices, Miller indices
  • Bonding in solids
  • Band structures: Metals, insulators, semiconductors

Spectroscopy 

  • Absorption
  • Fluorescence
  • Phosphorescence

Nanocrystals

  • Preparation
  • Properties 
  • Assembly

Nanocrystal based Devices

  • Dye sensitised solar cells
  • Photocatalytic breakdown: Bioremediation

Conjugated Polymer based Devices

  • OLED fabrication
  • OLED characterisation

Nanotechnology and the Environment 

  • Nanoparticles: Zero valent metal technology
  • Environmental assessment
  • Biouptake and accumulation

TY6002 Structural and Spectroscopic Characterisation at the Nanoscale

 Module Objectives:

  • Identify the relevant length and energy scales associated with each technique.

  • Analyse the operating principle of each technique.

  • Describe the type of data each technique provides, e.g., morphology, crystal structure, elemental or chemical analysis, electronic structure analysis.

  • Describe the measurement environment (including sample preparation). 

  • List the typical resolution obtainable for each technique and outline factors influencing the ultimate resolution. 

  • Summarise the strengths and weaknesses of each technique.

"Structural Characterisation at the Nanoscale" (21 lectures - Aidan Quinn)

Introduction

  • General classification of characterisation methods

  • Overview of scattering and imaging physics

  • Overview of surface physics and vacuum technology

Electron microscopy

  • Scanning electron microscopy (SEM)

  • Transmission electron microscopy (TEM) 

Spectroscopy and diffraction

  • Auger electron spectroscopy

  • X-ray fluorescence and X-ray photoelectron spectroscopy (XRF, XPS)

  • Electron and X-ray diffraction

  • Photon spectroscopy

Scanning probe techniques

  • Scanning tunnelling microscopy and spectroscopy (STM, STS)

  • Atomic force microscopy (AFM) and related techniques

  • Near-field scanning optical microscopy (NSOM)

Surface analysis and depth profiling


CM 4111 Analysis of solid materials

Module Objective: To provide students with experience and understanding of modern methods for material analysis.

Module Content: Introduction to solids analysis, Powder X-ray diffraction, electron microscopy, thermal methods. Surface analysis, XPS, AES and SIMS. Spectroscopy including FTIR, DRIFTS, NIR and Raman, atomic absorption.

"Electron Microscopy" (12 lectures Daniela Iacopino)

Introduction

  • Length scales

  • Introduction to surface science

  • General considerations about imaging

  • Review of Quantum Mechanics – electrons as waves

  • General classification of characterisation methods

  • Overview of scattering and imaging physics

Electron Microscopy

  • Scanning Electron Microscopy (SEM) introduction
  • SEM: technique and instrument description
  • SEM: range of samples and sample preparation.
  • Focused Ion Beam (FIB): technique and sample preparation
  • SEM: Electron Diffraction (SEM-ED)
  • Transmission Electron Microscopy (TEM): introduction
  • TEM: technique and instrument description
  • TEM: range of samples and sample preparation

Scanning Probe Techniques

  • Scanning Tunneling Microscopy (STM): introduction
  • STM: technique and instrument description
  • STM: range of samples and sample preparation
  • Atomic Force Microscopy (AFM): introduction
  • AFM: technique and instrument description
  • AFM: range of samples and sample preparation

Review & outlook


Course materials are available on the UCC Blackboard system

 

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